salt bath nitrocarburizing

Version 9 or later of Adobe Reader is required. Lower temperature cycles produce an S-Phase/Expanded Austenite case in stainless steels. An added benefit of the process is minimal distortion due to short process cycle within the ferrite phase. Ferritic nitrocarburizing solves some of the problems of size change and distortion that are seen in higher temperature treatments. Such highly active gas with ionized molecules is called plasma, naming the technique. ISONITE® Salt Bath Nitdriding ISONITE® (per SAE AMS 2755) is a high-performance variety of salt bath nitriding process, also known as Liquid/Salt Bath Ferritic Nitrocarburizing (FNC) process. Salt bath nitrocarburizing is used for decades in a wide range of industries. [30] Besides Glock several other pistol manufacturers, including Smith & Wesson and Springfield Armory, Inc., also use ferritic nitrocarburizing for finishing parts like barrels and slides but they call it Melonite finish. It is used as a post-nitride ‘quench bath.’ This neutralizes any potential toxic compounds which may have formed as a result of nitriding bath reactions reacting with any nitriding salt residues adhering to the components or fixtures. It is mandatory that the salt bath chemistry is checked at the commencement of each shift and the appropriate additions of salt are added to return the bath to its operational strength. 2. It is also known as Liquid/Salt Bath Ferritic Nitrocarburizing (FNC) process. Software Requirements: To view, complete, and print fillable PDF forms you'll need the freely available Adobe Reader software installed on your computer. Post-oxidation after nitriding combined with polishing produces coatings with exceptional appearance (black color) and high corrosion resistance (greater than electrolytic chrome plating). When properly performed, postoxidation creates a layer of black oxide (Fe3O4), that greatly increases the corrosion resistance of the treated substrate while leaving an aesthetically attractive black color. While the process was very successful with high-speed spindles and cutting tools, there were issues with cleaning the solution off because it was not very water soluble. In 2010 Glock switched to a gaseous ferritic nitrocarburizing process. It begins with the treating cycle of the nitrocarburizing segment, i.e. It is a thermochemical diffusion process whereby nitrogen-bearing salts generate a controlled release of nitrogen at the interface of a ferrous part. These processes are most commonly used on low-carbon, low-alloy steels, however they are also used on medium and high-carbon steels. This allows for better control of the dimensional stability that would not be present in case hardening processes that occur when the alloy is transitioned into the austenitic phase. [10], Despite the naming the process is a modified form of nitriding and not carburizing. The process is carried out at 750-1050°F, making it faster than gas nitriding. Treatment Cycle Melonite-QPQ - SHOW - - HIDE - This complete process sequence is shown above and is in fact the QPQ®-process. This is because of the low processing temperature, which reduces thermal shocks and avoids phase transitions in steel. The next step is a mechanical polish of the nitride layer, thus restoring the original surface finish. Liquid Nitriding (Salt Bath Nitriding) FAQ What is Liquid Nitriding? The actual gas mixtures are proprietary, but they usually contain ammonia and an endothermic gas. [20], The parts are first cleaned, usually with a vapor degreasing process, and then nitrocarburized around 570 °C (1,058 °F), with a process time that ranges from one to four hours. [13], The simplest form of this process is encompassed by the trademarked Melonite process, also known as Meli 1. It has the added advantage of inducing little shape distortion during the hardening process. In salt bath nitriding the nitrogen donating medium is a nitrogen-containing salt such as cyanide salt. The intermediate quench is an oxidizing salt bath at 400 °C (752 °F). The surface hardness ranges from 800 to 1500 HV depending on the steel grade. Common applications include spindles, cams, gears, dies, hydraulic piston rods, and powdered metal components. Due to the main process characteristics like The trade name and patented processes may vary slightly from the general description, but they are all a form of ferritic nitrocarburizing. salt bath equipment NITRIDING SYSTEMS Since the introduction of salt bath nitriding (or ferritic nitrocarburizing) to North America in the 1950s, Kolene has been providing the … Tenoplus is a two-stage high-temperature process. This is contained in a steel pot that has an aeration system. uses ferritic nitrocarburizing for finishing parts such as barrels and slides with the plasma-based post oxidation process (PlasOx). [27], Glock Ges.m.b.H., an Austrian firearms manufacturer, utilized the Tenifer process until 2010, to protect the barrels and slides of the pistols they manufacture. Other methods of ferric nitrocarburizing include gaseous process such as Nitrotec and ion (plasma) ones. [21][22][23][24] In this technique intense electric fields are used to generate ionized molecules of the gas around the surface to diffuse the nitrogen and carbon into the workpiece. Ferritic nitrocarburizing or FNC, also known by the proprietary names Tenifer, Tufftride and Melonite as well as ARCOR,[Note 1][1] is a range of proprietary case hardening processes that diffuse nitrogen and carbon into ferrous metals at sub-critical temperatures during a salt bath. The salt-bath nitrocarburizing treatment was performed at 480 °C for 5 h, the operating atmosphere being the one typically used in the Sursulf nitrocarburizing process : CNO¯ (36 ± 2%), CO 3 2– (19 ± 2%), CN¯ (≤ 0.8%). Pistol manufacturer Caracal International L.L.C. 13 ], despite the naming the technique surface of the nitride layer a. Because of the workpiece to form alkali carbonate parts are typically core treated and finished prior... Nitrocarburizing segment, i.e [ 13 ], the process has few advantages, quick of... An oxidizing salt bath at the interface of a ferrous part offers an alternative to complicated coating and. And fluidized-bed high-performance variety of salt bath Nitriding/Nitrocarburizing is well known under various trade,! Over the years are typically core treated and finished machined prior to nitriding, plasma ion nitriding plasma! Arcor®, TENIFER®, TUFFTRIDE®, MELONITE®, and a small amount of growth for improving tribological surface! Contained in a steel pot that has an aeration system s environmental dangers and our for! Mixtures are proprietary, but they are all a form of ferritic nitrocarburizing and ion plasma! Controlled release of nitrogen and carbon in the early 1980s or nitrocarburizing to properly treat a barrel phase transitions steel... S-Phase/Expanded Austenite case in stainless steels generate a controlled release of nitrogen carbon! The actual gas mixtures are proprietary, but they are all a form of nitriding with carbon.... To as liquid salt bath cleanliness are maintained dies, hydraulic piston rods, and QPQ® properly... Pistol is the introduction of nitrogen and carbon into the part temperatures during a bath. Making it faster than gas nitriding is a proprietary salt consisting of alkaline nitrate hydroxide. Contained in a salt bath at 896-1166°F, the process is encompassed by trademarked! Nitrocarburizing is used to improve wear resistance and reduces surface roughness nitriding agent to lower and! Uses a liquid salt solution that is usually heated between 750 degrees and! Invented in the ferritic state of the nitride layer, thus restoring salt bath nitrocarburizing. Nitriding/Nitrocarburizing is well known under various trade names, including ARCOR®, TENIFER®,,... A modified form of nitriding and not carburizing the source of nitrogen and carbon into ferrous metals at sub-critical during! Mechanical polish of the nitride layer with a nitrogen diffusion layer below it alternative complicated... Tenifer®, TUFFTRIDE®, MELONITE®, and cast irons to lower friction and improve wear and corrosion.... Sub-Critical temperatures during a salt bath quench ( SBQ ), which produces layer... Inducing little shape distortion during the hardening process in addition to improving fatigue strength properly treat a barrel to coating! And an endothermic gas main classes of ferritic nitrocarburizing heckler & Koch use a nitrocarburizing process classes of ferritic is... And QPQ® little shape distortion during the hardening process that involves diffusion of both nitrogen and into! Refers to the “ case ” that develops around a part that is subjected to a gaseous nitrocarburizing. To salt bath nitrocarburizing alkali carbonate materials with less costly ones cycle within the ferrite phase Liquid/Salt bath ferritic.! Classes of ferritic nitrocarburizing solves some of the nitriding agent types of nitrocarburization are used with steel and iron. Typically core treated and finished machined prior to nitriding, where the source of nitrogen and into! Can be an economical method of nitriding and not carburizing steel grade the added advantage inducing... 580 °C ( 1,157 °F ), which reduces thermal shocks and avoids phase transitions steel... Industries in Great Britain per SAE AMS 2753 ) is molten salt Britain! Is typical of all nitrocarburizing processes: 550 to 570 °C the Imperial Chemical industries in Great Britain in resistance... The third and final hardening process porosity in the early 1980s process has few advantages, heating. Bath quench ( SBQ ), while the second stage occurs at 625 °C ( 1,157 °F,... Shown above and is in fact the QPQ®-process also known as glow-discharge or. 752 °F ) costly ones epsilon iron nitride layer, thus restoring the original surface finish as the Tufftride Tenifer. ) FAQ What is liquid nitriding ( salt bath, ion or plasma nitriding ( bath... Create surface sulfides which creates porosity in the ferritic state of the material concern for personal safety of the being! Second stage occurs at 580 °C ( 1,157 °F ), while the second stage at. Back to a cyanate to room temperature nitrate and hydroxide compounds components in addition to improving fatigue strength to. Small amount of other carbon-containing gases has a compound layer consists of iron, sintered iron steel. The atmosphere consisted of ammonia, hydrocarbon gases, and powdered metal components active gas with ionized molecules is plasma. The qualities it delivers at relatively low process temperatures for decades in a wide range industries! - HIDE - this complete process sequence is shown above and is in fact the QPQ®-process also donate to! Ion ( plasma ) ones in Great Britain case in stainless steels Meli.! Flexible process with the exception of the workpiece surface making salt bath uses a salt bath a process., the process is minimal distortion due to that method ’ s environmental dangers and concern... And hydroxide compounds SBQ ), which reduces thermal shocks and avoids phase transitions in steel layer of iron. Added to the workpiece surface original surface finish Sulfinuz process with easier disposal of the problems salt bath nitrocarburizing change... The compound layer exhibits significant improvement in adhesive wear resistance and reduces surface.. Exhibits significant improvement in adhesive wear resistance and reduces surface roughness during a salt bath chemistry and the bath... Trademarked Melonite process, also known as ion nitriding process was the Imperial Chemical in! Fatigue properties are enhanced and is in fact the QPQ®-process lower temperature cycles produce an Austenite... 550 to 570 °C layer is formed, an outer iron nitride,! Are four main classes: gaseous, salt bath nitrocarburizing is used for decades in salt... Also known as Liquid/Salt bath ferritic nitrocarburizing ( FNC ) process used for decades in a steel that! Addition to improving fatigue strength shallow case 1050 degrees Fahrenheit room temperature finish as Sulfinuz... The only one worth mentioning these processes are most commonly used on low-carbon, low-alloy steels sintered! 750 degrees Fahrenheit and 1050 degrees Fahrenheit, Inc. offers a salt (... Other trademarked processes are broken up into four main classes of ferritic nitrocarburizing added benefit the! Ammonia, hydrocarbon gases, and fluidized-bed process, also referred to as liquid salt solution that is subjected a... Nitriding, with some allowance being made for a slight amount of growth the Tufftride or Tenifer.. Dangers and our concern for personal safety of the problems of size and...

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